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Beilstein J. Org. Chem. 2015, 11, 1809–1814, doi:10.3762/bjoc.11.196
Graphical Abstract
Figure 1: ‘ITent’ family of ligands, including IPr. First row: percentage buried volume (% Vbur) calculated i...
Scheme 1: Synthesis of gold complexes bearing the ITent ligands.
Scheme 2: Silver-free synthesis of [Au(ITent)(NTf2)] complexes.
Beilstein J. Org. Chem. 2011, 7, 892–896, doi:10.3762/bjoc.7.102
Scheme 1: Silver-free C–H functionalisation using [Au(OH)(IPr)].
Scheme 2: C–H functionalisation of 2 using gold-phosphine complexes and a silver additive.
Figure 1: X-ray structure of [Au(OPiv)(IPr)] 3. Thermal ellipsoids are shown at the 50% probability level. H ...
Scheme 3: Carboxylation of 2 using 1 and Ag2O.